Large electro‐optic activity and enhanced temporal stability of methacrylate‐based crosslinking hyperbranched nonlinear optical polymer

A methacrylate‐based crosslinking hyperbranced polymers have been synthesized through initiator‐fragment incorporation radical polymerization and used for the temperature stable electro‐optic (EO) polymer application. This polymer consists of methyl methacrylate, 2‐metacryloxyethyl isocyanate, and ethylene glycol dimethacrylate (EGDMA) monomers. The use of EGDMA as a bifunctional unit resulted in the solvent‐soluble crosslinking hyperbranched chain, so that the EO polymer enhanced glass transition temperatures. A phenyl vinylene thiophene vinylene bridge nonlinear optical chromophore was attached to the polymer backbone as the side‐chain by a post‐functionalization reaction. The loading concentration of the chromophore was varied between 30 and 50 wt % by simply changing the mixing ratio of the precursor polymer to the chromophore. The synthesized EO polymers produced optical quality films with a light propagation loss of 0.61 dB/cm in a slab waveguide at 1.31 μm. The electrically poled film had an EO coefficient (r₃₃) of 139 pm/V at 1.31 μm. The EO crosslinking hyperbranced polymer had a high‐glass transition temperature of 170 °C, and exhibited excellent temporal stability of the EO activity at 85 °C for 500 h. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

Reagentless Bioluminescent Sensor for NADH

Abstract

A reagentless fiber optic biosensor specific for NADH, associated with flow injection analysis and based on bacterial bioluminescence is described. Only a buffer solution as flowing stream is required for the probe which works without supply of its coreactants (FMN and N-decyl-aldehyde). These are coentrapped in a poly(vinyl)alcohol (PVA) matrix which allows their internal release in the vicinity of the immobilized enzymes. Two PVA matrices differing by the reticulation process have been tested : first, by polymerization with glutaraldehyde and secondly, by a cyclic freezing-thawing process. The self-containment working time was estimated at 1 and 1.5 h of continuous measurements, respectively. NADH was determined using flow injection analysis. The sensor gave excellent reproducibility (RSD ≤ 3%) in the linear dynamic range 5 — 500 pmol with an average cycle-time of 2.5 min.     

Rate type constitutive equations for fiber reinforced nonlinearly vicoelastic solids using spectral invariants

In this paper we are interested in developing constitutive equations for fiber-reinforced nonlinearly viscoelastic solids. It has been shown that constitutive equations for such bodies can be expressed in terms of a complete minimal set of 18 classical invariants associated with deformation and fiber orientation. In this paper, we give an alternative formulation using a set of spectral invariants. It is shown via the use of spectral invariants that only 11 of the 18 classical invariants are independent. We analyze the spectral invariants for two illustrative deformation gradients: (i) simple tension, and (ii) simple shear.     

基于频带分解和距离加权的单矢量水听器浅海被动测距方法研究

本文针对浅海环境下中低频宽带脉冲声源被动测距问题, 提出了一种声压和水平振速联合处理的被动测距方法. 在浅海波导中, 声压和质点振速的自相关函数卷绕(warping)谱具有稳定的频率特征. 声压和水平振速的自相关卷绕谱具有相同的准线谱特征, 垂直振速自相关卷绕谱具有宽谱叠加线谱的特征, 与声压自相关卷绕谱相比, 其尖峰个数比更多, 且尖峰宽度更宽. 利用引导源, 本文提出了基于频带分解和距离加权的声压和水平振速联合被动测距方法. 利用该方法对2008年冬季青岛海域综合实验中单矢量水听器接收的气枪信号进行处理, 结果表明, 该方法能够实现气枪声源的有效测距. 与传统单声压水听器被动测距方法相比, 该方法可以有效减小代价函数的主瓣宽度、提高测距精度.     

编码孔径光谱成像仪光学简化彗差对图谱反演误差分析

编码孔径光谱成像技术是近年来发展起来的一种新型光谱成像技术, 该技术在一次像面采用特定的编码模板对目标进行编码, 结合特殊的采样成像方式, 获得满足景物重构的采样数据量, 实现了空间信息和光谱信息的高精度重构, 具有高光通量、高信噪比等优势.但该技术实际的光学系统设计, 以及相应加工和装调过程中各种误差的存在, 将逐一传递反映到探测器精度与编码后图谱采样精度的不匹配, 这会引发最终重构图谱质量降低.本文侧重分析研究光学系统设计和研制装调中光学彗差相对设计值间存在的偏差, 通过几何光线追迹与波前像差联合计算的方法, 在成像面仿真出不同数值程度的彗差矩阵, 并以此来分析不同彗差下对重构图像质量的影响结果.并用其分析结论作为依据, 改进了编码孔径光谱成像仪的设计和研制, 提供了相应图像成像反演结果, 由此确保了编码孔径光谱成像仪的成像优势.     

单矢量水听器估计目标方位的方法与实验

为评估基于单矢量水听器的方位估计能力,在黄海海域对矢量水听器进行实验。矢量水听器吊放于接收船尾部,采用平均声强器和复声强器方位估计方法,并提出以概率密度值最大的方位角作为目标方位估计值的具体处理准则,对恒定方向、匀速行驶的目标船方位进行估计,并求出两种方法的方位估计误差。结果表明,水听器布放深度10 m时,对正横距离为0.42 km的航速10 kn的目标船,平均声强器方法的水平方位角估计误差18°,极角估计误差为5°,可以在离目标船最远1.17 km处估计其方位;复声强法的水平方位角估计误差为13°,极角估计误差为8°,可以在离目标船最远2.35 km处估计其方位。在有接收船的噪声干扰情况下,复声强器比平均声强器方法估计的方位更准确,可以对更远处的噪声源进行方位估计。     

光纤传感器测量FRP加固结构的损伤

A distributed fiber optic sensor is developed for condition monitoring of civil infrastructure sys-tems. The fiber optic sensor is especially useful in applications involving structures strengthened by fiberreinforced polymer (FRP) composites. The sensor principles are simple and therefore, practical for detec-tion of cracks, debonding and deformation measurements. Structural monitoring capability of the sensor     

声焦散线及其与应力强度因子的关系

 根据焦散线的形成原理，以及含I型裂纹试件受力前后光程差与 声程差表达式的相似性，提出了声焦散线的概念，得到了声焦散线沿 横向最大尺寸与应力强度因子的关系，为通过声焦散线法确定应力强 度因子打下了基础.     

基于光纤智能夹层传感结构的应力测量研究

制作了一种模块化的光纤传感夹层,对夹层内的光纤传感器的应力特性进行了实验研究。分析了应变对传感系数的影响,对埋入到光纤智能夹层中的两种光纤传感器的输出特性进行了比较。实验结果表明:光纤Bragg光栅传感器的波长漂移与应变之间具有理想的线性关系,但应变灵敏度由1.2pm/με降至1.15pm/με;由于制作工艺的局限,对于非本征F-P光纤传感器,当应变达到350με后,应变与载荷具有较好的线性响应。与非本征F-P光纤传感器相比,光纤Bragg光栅传感器是光纤智能夹层首选的应变传感器。将埋入了Bragg光栅传感器的智能夹层粘贴于某型飞机的翼-身连接构件内部进行监测,实验结果为光纤智能夹层应用于复合材料结构的应变监测提供了参考。     

A Cosserat shell model for interphases in elastic media

This study is concerned with the modeling of interphases in elastic media in general, and in composite materials in particular. The aim is to replace a boundary value problem consisting of a three-phase configuration, say that of fiber-interphase-matrix, by a simpler problem which involves the fiber and matrix only, plus certain matching conditions which simulate the interphase. The simplest of such known representations replaces a thin interphase by a “perfect contact interface” (a single surface) across which the displacements and tractions are assumed to be continuous. Another classical model replaces a thin and soft interphase by a “spring-type interface”, across which the tractions are continuous, but the displacement field undergoes a discontinuity. In the present paper, a Cosserat shell model of the interphase is derived which successfully models the original interphase in a unified manner, for the full range of its material parameters relative to those of the neighboring media. The model is derived in the setting of three-dimensional linear elasticity with small deformations and displacements. Comparisons with an existing exact solution of a coated fiber in an infinite matrix show that it performs extremely well even for moderately thick interphases.